| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Sarah Maseboka Thamaha | - | Member | — | People's Assembly |
| Sara Links | - | Member | — | People's Assembly |
| Sazingane Fetman | - | Member | — | People's Assembly |
| Segametsi Maureen Pholose | - | Member | — | People's Assembly |
| Selekiso Edward Kepadisa | - | Member | — | People's Assembly |
| Sello Joseph Makhurupetji | - | Member | — | People's Assembly |
| Sibonelo Hopewell Mthembu | - | Member | — | People's Assembly |
| Selata Nkwane | - | Member | — | People's Assembly |
| Shiko Tebogo Matsomane | - | Member | — | People's Assembly |
| Lyndall Fanisa Shope-Mafole | - | Member | — | People's Assembly |
| Sibusiso Samuel Gwengu | - | Member | — | People's Assembly |
| Simon Kgaregi Shai | - | Member | — | People's Assembly |
| Sindile Faku | - | Member | — | People's Assembly |
| Sindiswa Patricia Rwexana | - | Member | until Nov 2013 | People's Assembly |
| Siphiwo Charles Mangena | - | Member | — | People's Assembly |
| Sizwe Lulama Qwalela | - | Member | — | People's Assembly |
| Solomon May | - | Member | — | People's Assembly |
| Sonwabo Madolo | - | Member | — | People's Assembly |
| Stephanie Mary Breedt | - | Member | — | People's Assembly |
| Stephanus Jan Coetzee Van Wyk | - | Member | — | People's Assembly |
| Susan Nagoor | - | Member | — | People's Assembly |
| Swaphi Hendrick Plaatjie | - | Member | — | People's Assembly |
| Siphiwe Ernest Nomandindi | - | Member | — | People's Assembly |
| Sizwe Moses Zulu | - | Member | Mar 2014 | People's Assembly |
| Sofie Van Staden | - | Member | — | People's Assembly |