| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Sesana Reinolda Dhlamini | - | Member | — | People's Assembly |
| Shela Caroline Majoko | - | Member | — | People's Assembly |
| Sibusiso Peter Hadebe | - | Member | — | People's Assembly |
| Sihle Kevin Ndlela | - | Member | — | People's Assembly |
| Sigamoney Richard Pillay | - | Member | — | People's Assembly |
| Silumko Khetokuhle Einstein Mabona | - | Member | — | People's Assembly |
| Simcelile Rubela | - | Member | — | People's Assembly |
| Simphiwe Larry Ntinge | - | Member | — | People's Assembly |
| Sincede Mapukata | - | Member | — | People's Assembly |
| Sindisiwe Priscilla Tshabalala | - | Member | — | People's Assembly |
| Sinenhlanhla Petros Ntshangase | - | Member | — | People's Assembly |
| Sinethemba Mzuzu | - | Member | — | People's Assembly |
| Singqi Mvumbi | - | Member | — | People's Assembly |
| Siyabulela Mcandy Peter | - | Member | — | People's Assembly |
| Smanga Moses Nxanga | - | Member | — | People's Assembly |
| Songezo Walter Mpeteng | - | Member | — | People's Assembly |
| Sonja Yolanda Maasdorp | - | Member | — | People's Assembly |
| Soyikeni Nimrod Mlindi | - | Member | — | People's Assembly |
| Siphiwo Mavuso | - | Member | — | People's Assembly |
| Sipho Christopher Tengile | - | Member | — | People's Assembly |
| Sipho Gift Sibiya | - | Member | — | People's Assembly |
| Siyabonga Mlilo | - | Member | — | People's Assembly |
| Snazo Mabumbulu | - | Member | — | People's Assembly |
| Soneth Mokoena | - | Member | — | People's Assembly |
| Sonny-Boy David Shelembe | - | Member | — | People's Assembly |