| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Sandile Charles Eland | - | Member | — | People's Assembly |
| Sandisiwe Xheke | - | Member | — | People's Assembly |
| Sapho Matutu | - | Member | — | People's Assembly |
| Sarah Alexandra Dlamini | - | Member | — | People's Assembly |
| Sarah Kediemetse Molale | - | Member | — | People's Assembly |
| Scott Taylor Peek | - | Member | — | People's Assembly |
| Secwakae Jacob Leeuw | - | Member | — | People's Assembly |
| Selaelo Ludwiq Mugwena | - | Member | — | People's Assembly |
| Selinah Mathabela Nyama | - | Member | — | People's Assembly |
| Sethu Sibusisiwe Nguna | - | Member | — | People's Assembly |
| Setjakadume Enos Ramaepadi | - | Member | — | People's Assembly |
| Sibusiso Aaron Phungula | - | Member | — | People's Assembly |
| Sifiso Siziba | - | Member | — | People's Assembly |
| Sikhumbuzo Richard Sikondlo | - | Member | — | People's Assembly |
| Sasa Mabel Chiloane | - | Member | — | People's Assembly |
| Saul Francesco Uys Rootenberg | - | Member | — | People's Assembly |
| Sello Victor Thobakgale | - | Member | — | People's Assembly |
| Sibonelo Sabelo Khuzwayo | - | Member | — | People's Assembly |
| Sidney Nicholas Moagi | - | Member | — | People's Assembly |
| Simphiwe Mkize | - | Member | — | People's Assembly |
| Smith Otladisa Marope | - | Member | — | People's Assembly |
| Somila Brian Sentwa | - | Member | — | People's Assembly |
| Siyabulela Hans | - | Member | — | People's Assembly |
| Sontaha Lazarus Sithole | - | Member | — | People's Assembly |
| Sipho Elphus Sushii Mbokane | - | Member | — | People's Assembly |