| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Sesitoa Mountbatten Rasethaba | - | Member | — | People's Assembly |
| Sikhumbuzo Vusumuzi Emmanuel Mchunu | - | Member | — | People's Assembly |
| Segapu Martha Mahapa | - | Member | — | People's Assembly |
| Sekwele Maria Mthembu | - | Member | — | People's Assembly |
| Seswantsho Mathews Malemela | - | Member | — | People's Assembly |
| Simon Molatlhegi Sethepo | - | Member | — | People's Assembly |
| Siphamandla Ignatious Nene | - | Member | — | People's Assembly |
| Sipho Gavin Vanga | - | Member | — | People's Assembly |
| Sipho Sigabi | - | Member | — | People's Assembly |
| Stanley Sipho Sigotyana | - | Member | — | People's Assembly |
| Stephen Wauchope | - | Member | — | People's Assembly |
| Strike Edward Thokoane | - | Member | — | People's Assembly |
| Sunshine Lindiwe Samphiwa Mbele | - | Member | — | People's Assembly |
| Stella Khanyile | - | Member | — | People's Assembly |
| Stiph Sibeko | - | Member | — | People's Assembly |
| Siphesihle Mduduzi Zulu | - | Member | — | People's Assembly |
| Snenhlanhla Prudencia Mngoma | - | Member | — | People's Assembly |
| Solomon Magagane | - | Member | — | People's Assembly |
| Steven Sonnyboy Seahlodi | - | Member | — | People's Assembly |
| Taole Winnett Matsoko | - | Member | — | People's Assembly |
| Tebogo Daniel Ramogogane | - | Member | — | People's Assembly |
| Tebogo William Kotsedi | - | Member | — | People's Assembly |
| Tete Gavin Cornelius Modikoe | - | Member | — | People's Assembly |
| Thabiso John Mashiya | - | Member | — | People's Assembly |
| Thapelo Jacob Maleka | - | Member | — | People's Assembly |